The debris was spotted from the air by Brazilian military pilots searching 410 miles (650 kilometers) north of the Brazilian island of Fernando de Noronha, roughly along the path that the jet was taking before it disappeared with 228 people on board, said Air Force spokesman Jorge Amaral.
There were no signs of life.
Amaral said authorities would not be able to confirm that the debris is from the plane until they can retrieve some of it from the ocean for identification. Brazilian military ships are not expected to arrive at the area until Wednesday.
The discovery came more than 24 hours after the jet bound from Rio to Paris went missing, with all feared dead.
Rescuers were still scanning a vast sweep of ocean extending from far off northeastern Brazil to waters off West Africa. The 4-year-old Airbus A330 was last heard from at 0214 GMT Monday (10:14 p.m. EDT Sunday).
Investigators on both sides of the ocean were trying to determine what brought it down. Potential causes included shifting winds and hail from towering thunderheads, lightning or a combination of other factors.
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